Borates II. Borate Glasses, Crystals & Melts

A. C. Wright, S. A. Feller and A. C. Hannon

Proceedings of the Second International Conference, 22-25 July 1996, Abingdon, UK.
1997, 234 mm × 156 mm, 570 pages, black and white illustrations,
ISBN 0-900682-23-X
£60.00 (£50.00 SGT members)

Contents
Back

  Page
Professor Phillip J. Bray iii
Foreword iv
1. NMR Spectroscopy
Session Chairs: S.A. FELLER (Coe College, Cedar Rapids, IA, USA) & A.C. WRIGHT (University of Reading, UK)
 
NMR and NQR studies of borates and borides (Plenary Lecture)
P.J. BRAY (Brown University, Providence, RI, USA)
1
High-resolution NMR studies of borate glass structure (Invited)
J.W. ZWANZIGER, R.E. YOUNGMAN & M. BRAUN (Indiana University, Bloomington, USA)
20
NMR studies of borate and borosilicate glass systems in Korea (Abstract Only)
C. RHEE (Korea Research Institute of Standards and Science, Taejon, Korea)
33
Temperature effects on borate melt structure and dynamics: NMR studies
J.F. STEBBINS & S. SEN (Stanford University, CA, USA)
34
Studies of the structure of Li2O-B2O3-Al2O3 glasses using 11B NMR technique
H.-T. KIM, S.-J. CHUNG (Chonnam National University, Kwang-ju, South Korea) & M.-J. Park (Korea University, Seoul, South Korea)
42
   
2. Paradoxes of the Vitreous State
Session Chair: N.M. VEDISHCHEVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
 
Some paradoxes of borate glasses and melts (Invited)
E.A. PORAI-KOSHITS (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia) & A.C. WRIGHT (University of Reading, UK)
51
The boron oxide "anomaly" revisited
M.C. WEINBERG, D.R. UHLMANN & W.H. POISL (University of Arizona, Tucson, USA)
63
Low-Q features in diffraction data for borate glasses and crystals - an examination of similarities in medium-range structures
P.H. GASKELL (University of Cambridge, UK)
71
The interrelationship between the structures of borate glasses and crystals
A.C. WRIGHT (University of Reading, UK), N.M. VEDISHCHEVA & B.A. SHAKHMATKIN (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
80
   
3. Structure, Inhomogeneity & Phase Separation
Session Chair: N.M. VEDISHCHEVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
 
Structural and chemical inhomogeneities in borate glasses (Invited)
V.V. GOLUBKOV (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
88
Cation and network structure in binary potassium borate glasses
N. UMESAKI, D.A.H. CUNNINGHAM, N. KAMIJO (Osaka National Research Institute, Japan), K. HANDA (Ritsumeikan University, Siga, Japan) & Y. IWADATE (Chiba University, Japan)
99
Temperature dependence of the relaxation compressibility of boron oxide based on visible light scattering data
N.A. BOKOV & N.S. ANDREEV Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
107
A structural study of Bi2O3-B2O3 glasses
E.M. GATTEF, V.V. DIMITROV, Y.B. DIMITRIEV(University of Chemical Technology & Metallurgy, Sofia, Bulgaria) & A.C. WRIGHT (University of Reading, UK)
112
Crystal structure and thermal behaviour of rubidium borates
R.S. BUBNOVA, I.G. POLYAKOVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia), S.K. FILATOV & M.G. KRZHIZHANOVSKAYA (Sankt Petersburg University, Russia)
120
   
4. Spectroscopic Techniques
Session Chair: E.I. KAMITSOS (National Hellenic Research Foundation, Athens, Greece)
 
Borate structures by vibrational spectroscopy (Invited)
G.D. CHRYSSIKOS & E.I. KAMITSOS (National Hellenic Research Foundation, Athens, Greece)
128
Inelastic neutron scattering techniques for studying superstructural units in borate glasses
R.N. SINCLAIR, A.C. WRIGHT, A.J. WANLESS (University of Reading, UK), A.C. HANNON (Rutherford Appleton Laboratory, Chilton, UK), S.A. FELLER, M.T. MEYHEW, B.M. MEYER, M.L. ROYLE, D.L. WILKERSON, R.B. WILLIAMS & B.C. JOHANSON (Coe College, Cedar Rapids, IA, USA)
140
n(=1,2,3)-dimensional Fourier transform electron paramagnetic resonance (FT-EPR) spectroscopy measurements in the B2O3-Li2O system and MO calculations
G. KORDAS (National Center for Scientific Research "Demokritos", Athens, Greece)
148
Structural investigations of lead and strontium borate glasses
T. HÜBERT, U. HARDER, G. MOSEL & K. WITKE (Bundesanstalt für Materialforschung und -prüfung, Berlin, Germany)
156
High-temperature Raman spectral studies of various borate-containing glasses (Invited)
R.A. CONDRATE, Sr. & A.K. JILLAVENKATESA (New York State College of Ceramics, Alfred, USA)
164
X-ray photoelectron spectroscopy of borate glasses
S. MATSUMOTO, Y. MIURA, C. MURAKAMI & T. NANBA (Okayama University, Japan)
173
Velocity of sound and elastic properties of alkali borate glasses
M. KODAMA (Kumamoto Institute of Technology, Japan) & S. KOJIMA (University of Tsukuba, Japan)
181
   
5. Thermodynamics of Borate Systems
Session Chair: R.J. ARAUJO (Corning Inc, NY, USA)
 
Thermodynamics of borate melts and glasses (Invited)
B.A. SHAKHMATKIN, N.M. VEDISHCHEVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia) & A.C. WRIGHT (University of Reading, UK)
189
Structure and properties of multi-component borate glasses based on Raman spectroscopy and the chemical equilibrium concept
R. OTA, J. FUKUNAGA & T. WAKASUGI (Kyoto Institute of Technology, Japan)
199
Thermodynamic, acoustic and elastic properties of B2O3 glasses
M.A. RAMOS, S. VIEIRA (Universidad Autónoma de Madrid, Spain), C. PRIETO (Instituto de Ciencia de Materiales de Madrid, Spain) & J.F. FERNANDEZ (Universidad Autónoma de Madrid, Spain)
207
Simulation of the structure of borate glasses and melts on the basis of thermodynamics
N.M. VEDISHCHEVA, B.A. SHAKHMATKIN, M.M. SHULTZ (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia) & A.C. WRIGHT (University of Reading, UK)
215
   
6. Ternary Systems
Session Chair: R.J. ARAUJO (Corning Inc, NY, USA)
 
Alkali borosilicate systems: phase diagrams and the structure of glass
I.G. POLYAKOVA & E.V. TOKAREVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia)
223
Effect of mode of formation on the structure of borosilicate glasses
Y.B. DIMITRIEV, E.P. KASHCHIEVA, M.A. BURSUKOVA & P.D. HINKOV (University of Chemical Technology & Metallurgy, Sofia, Bulgaria)
231
Surface studies of borate glasses
C.G. PANTANO, D.M. BEALL & W. CERMIGNANI (Pennsylvania State University, USA)
239
Physical properties of alkali borosilicate glasses
S.A. FELLER, J. KOTTKE, J. WELTER, S. NIJHAWAN, R. BOEKENHAUER, H. ZHANG, D. FEIL, C. PARAMESWAR, K. BUDHWANI, M. AFFATIGATO, A. BHATNAGAR, G. BHASIN, S. BHOWMIK, J. MACKENZIE, M. ROYLE, S. KAMBEYANDA, P. PANDIKUTHIRA & M. SHARMA (Coe College, Cedar Rapids, IA, USA)
246
Crystallization kinetics in Cd, Sr and Ba borophosphate systems
G.A. SYCHEVA (Institute of Silicate Chemistry of the Russian Academy of Sciences, Sankt Petersburg, Russia) & V.N. SIGAEV (Mendeleev University of Chemical Engineering, Moscow, Russia)
254
   
7. Non-Oxide & Mixed Glasses
Session Chair: A.J. LEADBETTER (Institut Laue-Langevin, Grenoble, France)
 
Structure and properties of akali thioborate glasses: unique chemistries and unusual properties (Invited; Abstract Only)
S.W. MARTIN (Iowa State University of Science & Technology, Ames, USA)
262
Analytical and molecular orbital modelling approach to the chemical bonding states of F- ions in oxyfluoroborate glasses
S. HAYAKAWA & A. OSAKA (Okayama University, Japan)
263
Preparation of lithium chloroboracite by the sol-gel method
T. NAGASE, K. SAKANE & H. WADA (Shikoku National Industrial Research Institute, Takamatsu, Japan)
271
Densities of the alkali thioborate glasses as a function of short range order
M. ROYLE, J. CHO & S.W. MARTIN (Iowa State University of Science and Technology, Ames, USA)
279
   
8. Superionic & Related Systems
Session Chair: L.M. TORELL (Chalmers University of Technology, Göteborg, Sweden)
 
An XPS study of the chemical structure of AgI-Ag2O-B2O3 glasses
H. JAIN, A.C. MILLER (Lehigh University, Bethlehem, PA, USA), E.I. KAMITSOS & J.A. KAPOUTSIS (National Hellenic Research Foundation, Athens, Greece)
287
The role of silver in the structure of (AgI)x(Ag2O×nB2O3)1-x borate glasses and their fast ion conducting properties
F. ROCCA (Centro CNR-ITC di Fisica, Trento, Italy), G. DALBA, P. FORNASINI (Università di Trento, Italy) & F. MONTI (Università di Verona, Italy)
295
A structural study of silver borate glasses by infrared reflectance and Raman spectroscopies
J.A. KAPOUTSIS, E.I. KAMITSOS & G.D. CHRYSSIKOS (National Hellenic Research Foundation, Athens, Greece)
303
   
9. Industrial & Technological Applications
Session Chair: R. O’CONNOR (Borax Europe Ltd, Guildford, UK)
 
History of the use of B2O3 in commercial glass (Invited)
R.A. SMITH (U.S. Borax Inc., Valencia, CA, USA)
313
Microfloat technology - a new challenge to the production of hightech borosilicate flat glasses (Abstract Only)
T. KLOSS, K. SCHNEIDER, G. LAUTENSCHLÄGER (JENAer Glaswerk GmbH, Germany), P. KELLER, W. LINZ (Schott Glaswerke Mainz, Germany), T. KIMURA & Y. TAKAHASHI (Asahi Glass Corp, Tokyo, Japan)
323
The use of boron oxide in glass fiber formulations
F.L. HARDING, J.F. BAUER, H.H. RUSSELL III & X. XU (Schuller International, Littleton, CO, USA)
324
Influence of small quantities of boron oxide additives on the microstructure and optical properties of dental glass-ceramics
W. HÖLAND, M. FRANK & V. RHEINBERGER (IVOCLAR Ltd., Schaan, Liechtenstein)
332
Haloborate glass-ceramics as x-ray storage phosphors
K. PAPADOPOULOS & K. SIEBER (Eastman Kodak Co., Rochester, NY, USA)
340
   
10. Relaxation & the Glass Transition
Session Chair: C. RHEE (Korea Research Institute of Standards and Science, Taejon, Korea)
 
Liquid-glass transition in B2O3 (Invited; Abstract Only)
L. BÖRJESSON (Chalmers University of Technology, Göteborg, Sweden)
348
Relaxation processes in borate melts
B.J. REARDON, J. KIEFFER, J.E. MASNIK & J.D. BASS (University of Illinois, Urbana, USA)
349
High-pressure induced phenomena in glasses
M.I. KLINGER (Bar Ilan University, Ramat Gan, Israel) & S.N. TARASKIN (Moscow Engineering-Physics Institute, Russia)
357
The Bray and the Landa-Patashinskii models, and polymorphism in borosilicate glasses and melts
L.M. LANDA & K.A. LANDA (Lancer Tech, Inc., Greensburg, PA, USA)
364
   
11. Optical Spectroscopy & Defects
Session Chair: Y.B. DIMITRIEV (University of Chemical Technology & Metallurgy, Sofia, Bulgaria)
 
The structure of defects induced in silica glass by boron implantation
K. KAWAMURA, H. HOSONO, H. KAWAZOE, (Tokyo Institute of Technology, Japan), M. SETO & S. FUJITSU (Shonan Institute of Technology, Kanagawa, Japan)
370
Effect of the composition of some lead borate glasses containing uranium and tin ions on their optical absorption characteristics
M.M. MORSI & N. ABD-ELSHAFI (National Research Centre, Cairo, Egypt)
377
Hypersensitivity of neodymium ions in sodium borate, sodium silicate and sodium borosilicate glasses
K. GATTERER (Graz University of Technology, Austria)
384
Luminescence quenching mechanisms for g-irradiated barium aluminoborate glasses doped with Fe
W.M. PONTUSCHKA, M.I.T. OLIVEIRA (Instituto de Fisica da Universidade de São Paulo, Brazil) & S.M. DEL NERY (Universidade Estadual Paulista "Júlio Mesquita Filho", Guaratinguetá, Brazil)
392
Photostimulated luminescence of borate glasses doped with Ce3+ and Sm3+ ions
J. QIU, Y. SHIMIZUGAWA & N. SUGIMOTO (Hirao Active Glass Project, Kyoto, Japan) & K. HIRAO (Kyoto University, Japan)
399
   
12. Modelling & Computer Simulation
Session Chairs: S.A. FELLER (Coe College, Cedar Rapids, IA, USA) & A.C. WRIGHT (University of Reading, UK)
 
Ab initio based studies of borate glasses (Invited)
M. TETER (Corning Inc., NY, USA)
407
Ab initio molecular orbital calculations on the structure and the low-frequency vibrational modes in B2O3 and alkali borate glasses
T. UCHINO & T. YOKO (Kyoto University, Japan)
417
An investigation of the structure of vitreous boron trioxide by reverse Monte Carlo simulations
J. SWENSON & L. BÖRJESSON (Chalmers University of Technology, Göteborg, Sweden)
425
   
13. Poster Session  
Molecular dynamics simulation of PbO.xB2O3 glasses with bond angle constraint
Y. AKASAKA (Furukawa Electric Co. Ltd, Chiba, Japan) & I. YASUI (University of Tokyo, Japan)
435
Molecular dynamics simulation of B2O3 glass using a coordination dependent potential
B. PARK & A.N. CORMACK (New York State College of Ceramics, Alfred, USA)
443
Surface crystallization of CsLiB6O10 glass
Y. DING, Y. MIURA, S. NAKAOKA, T. NANBA & A. OSAKA (Okayama University, Japan)
453
Microstructure of low-melting B2O3-containing glassy coatings for traditional ceramics
S.P. DJAMBAZOV, Y.Y. IVANOVA, E.P. KASHCHIEVA & A.P. YOLEVA (University of Chemical Technology & Metallurgy, Sofia, Bulgaria)
461
XAFS studies of the local structure of CaO-K2O-B2O3 and K2O-B2O3 glasses
K. HANDA (Ritsumeikan University, Siga, Japan), N. UMESAKI, D.A.H. CUNNINGHAM, N. KAMIJO (Osaka National Research Institute, Japan) & Y. IWADATE (Chiba University, Japan)
468
Crystallization behaviour of some glasses in the systems Li2O-B2O3 and Li2O-B2O3-Al2O3
F.A. KHALIFA & H.A. EL BATAL (National Research Centre, Cairo, Egypt)
474
Effect of B2O3 on boron-containing metallic glasses based on cobalt
M.A. KHUSAINOV (Novgorod State University, Russia) & A.C. WRIGHT (University of Reading, UK)
484
Bioactivity of alkali and alkaline earth borosilicate glasses
A. OSAKA, S. HAYAKAWA, K. TSURU & C. OHTSUKI (Okayama University, Japan)
490
A comparison of the densities of lithium and sodium borate and silicate glasses with very high alkali contents
P. VENHUIZEN, A.M. PETERS, F. ALAMGIR, K. LOH, R.B. WILLIAMS & S.A. FELLER (Coe College, Cedar Rapids, IA, USA)
498
A proposed relationship between the position of the first neutron diffraction peak for alkali borate glasses and the separation between the modifying cations as found from density measurements
A.J. WANLESS, A.C. WRIGHT, R.N. SINCLAIR (University of Reading, UK), S.A. FELLER, R.B. WILLIAMS, B.C. JOHANSON & M.T. MAYHEW (Coe College, Cedar Rapids, IA, USA)
506
The abnormal properties of boron oxide in glass (Abstract Only)
J.J.L. YI (Circon ACMI, Stamford, CT, USA)
513
A vibrational spectroscopic study of alkaline earth borate glasses
Y.D. YIANNOPOULOS, E.I. KAMITSOS, G.D. CHRYSSIKOS & J.A. KAPOUTSIS (National Hellenic Research Foundation, Athens, Greece)
514
Author index 523
Subject index 529
Participants 545


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